Chlorido{μ-2,6-bis[(2-aminoethyl)iminomethyl]-4-chlorophenolato}-μ-oxido-dicopper(II) trihydrate
نویسندگان
چکیده
In the title dinuclear complex, [Cu(2)(C(14)H(20)ClN(4)O)ClO]·3H(2)O, one Cu(II) cation assumes a distorted square-planar coordination geometry and the other a distorted square-pyramidal coordination geometry. Both Cu(II) cations are N,N',O-chelated by one arm of the 2,6-bis-[(2-amino-eth-yl)imino-meth-yl]-4-chloro-phenolate anion, and one oxide anion bridges the two Cu(II) cations, forming a dinuclear complex. One of the Cu(II) cations is further coordinated by an Cl(-) anion in the apical direction. In the crystal, lattice water mol-ecules are linked with the complex mol-ecule via O-H⋯Cl hydrogen bonds while O-H⋯O hydrogen bonding occurs between lattice water mol-ecules , forming three-dimensional network structure.
منابع مشابه
Di-μ-chlorido-bis({9-[(2,6-diisopropylphenyl)iminomethyl]anthracen-1-yl}palladium(II))
The centrosymmetric title compound, [Pd(2)Cl(2)(C(27)H(26)N)(2)], was obtained by a C-H bond-activation reaction of a Schiff base ligand with Li(2)PdCl(4) in methanol, and was crystallized from dichloro-methane as orange crystals. The Pd atom displays a slightly distorted square-planar geometry, with the N- and C-atom donors in a cis arrangement.
متن کاملDi-μ-chlorido-bis({2-[(4-bromophenyl)iminomethyl]pyridine-κ2 N,N′}chloridomercury(II))
The unique Hg(II) ion in the title centrosymmetric dinuclear complex, [Hg(2)Cl(4)(C(12)H(9)BrN(2))(2)], is in a distorted trigonal-bipyramidal coordination environment formed by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg-Cl bonds is significantly longer than the other.
متن کاملDi-μ-chlorido-bis(chlorido{2-[(4-ethylphenyl)iminomethyl]pyridine-κ2 N,N′}copper(II))
The binuclear title complex, [Cu(2)Cl(4)(C(14)H(14)N(2))(2)], is located on a crystallographic inversion centre. The Cu(II) ion is in a distorted square-pyramid coordination environment formed by the bichelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Cu-Cl bonds is significantly longer than the other.
متن کاملDi-μ-chlorido-bis{[μ-1,8-bis(diisopropylphosphanyl)-9,10-dihydro-9,10-ethanoanthracene-κ2 P:P′]-μ-chlorido-μ-methylidene-dipalladium(II)} tetrahydrofuran pentasolvate
The title compound, [Pd(4)(CH(2))(2)Cl(4)(C(28)H(40)P(2))(2)]·5C(4)H(8)O, possesses a tetra-nuclear palladium core with four bridging chlorido ligands and two bridging methyl-ene units, as well as two bridging anthracene-based bis-phosphine ligands. This tetra-nuclear complex can be considered as being composed of two μ-chlorido-bridged LPd(2) units. The structural motif of these LPd(2) units s...
متن کاملμ-Oxido-bis{chlorido[tris(2-pyridylmethyl)amine]manganese(III)} bis(hexafluoridophosphate)
In the title compound, [Mn(2)O(C(18)H(18)ClN(4))(2)](PF(6))(2), the Mn atom is chelated by a tetra-dentate ligand via four N atoms, and further bonded to one chloride ion and one bridging oxide, to give a centrosymmetric cation and distorted octa-hedral coordination geometry.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012